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1 Denumire curs: MATERIALE MICRO SI MEZOPOROASE CU APLICATII IN CATALIZA Domeniul de CHIMIE licenta: Specializare: CHIMIE Tip disciplină: Optionala Nr. credite: 5 Anul de studiu: III Semestrul VI Ciclul: Licenţă (I) Timp alocat: Curs: 2 h x 10 săpt = 20 h Laborator: 2 h x 10.săpt = 20 h Forma verificare: Examen final 80 % Verificări pe parcurs 20 % Course name: MICRO AND MESOPOROUS MATERIALS FOR CATALYSIS Field of study: CHEMISTRY Specialization: CHEMISTRY Course type: Optional ECTS: 5 Year of study: III Semester: VI Program: Bachelor (I) Time allocated: Course 2 h x 10 weeks = 20 h Laboratory: 2 h x 10 weeks = 20 h Evaluation form Final examination 80 % Period aligned evaluation 20 % Cuvinte cheie Catalizatori microporosi. Zeoliti. Zeoliti modificati. Site moleculare. Argile structurate. Solide acide. Catalizatori mezoporosi. Solide redox. Hidrotalciti. Solide bazice. Keywords Microporous catalysts. Zeolites. Modified zeolites. Molecular sieves. Pillared clays. Acid solids. Mesoporous catalysts. Redox solids. Hydrotalcites. Basic solids. Obiectivele Cursului Studiul unor clase de materiale micro si mezoporoase urmarindu-se corelatia sinteza structura proprietati fizico-structurale proprietati catalitice. Course Objectives Study of some classes of micro and mesoporous materials following the correlation synthesis technique structure physico-structural properties catalytic properties. Competenţe acordate de absolvirea cursului Cursul dă o imagine generala despre materialele catalitice micro si mezoporoase si mecanismul functionarii lor in cataliza. Competences derived from the passing of the course The course gives a broad image on the micro and mesoporous catalytic materials and their working mechanism in catalysis. 1

2 Planul Tematic al cursului Nr. curs Tema cursului Nr. ore 1 Introducere. Micro, mezo si macroporozitate. Determinarea experimentala a 2 porozitatii. Efectul porozitatii asupra proprietatilor catalitice. 2 Materiale microporoase. Zeoliti. Compozitie. Structura. Sinteza. 2 3 Proprietatile zeolitilor. Aciditatea. Modificarea aciditatii. Selectivitatea 2 conformationala. Aplicatii in cataliza. 4 Site moleculare de tip aluminofosfat. Compozitie. Structura. Proprietati. 2 Aplicatii in cataliza. 5 Site moleculare pe baza de carbon. Sinteza. Structura. Aplicatii in cataliza. 2 6 Argile structurate. Preparare. Structura. Proprietati. Aplicatii in cataliza. 2 7 Materiale mezoporoase. Materiale mezoporoase de tip silice. Tehnici de 2 sinteza. Proprietati. Modificarea silicei mezostructurate prin incorporarea de heteroatomi in retea. Materiale mezostructurate fara siliciu. 8 Aplicatii in cataliza acida si cataliza redox. Grefarea catalizatorilor moleculari 2 pe suprafata materialelor mezostructurate. 9 Hidroxizi dubli stratificati. Compozitie. Structura. Tehnici de sinteza Bazicitatea hidrotalcitilor. Aplicatii in cataliza. 2 Contents of the course 1 Introduction. Micro, meso and macroporosity. Experimental measurement of 2 the porosity. Effect of porosity on catalytic properties. 2 Microporous materials. Zeolites. Composition. Structure. Synthesis. 2 3 Zeolites properties. Acidity. Acidity modification. The shape-selectivity of 2 zeolites. Applications in catalysis. 4 Aluminophosphate based molecular sieves. Composition. Structure. 2 Properties. Applications in catalysis. 5 Carbon-based molecular sieves. Synthesis. Structure. Applications in 2 catalysis. 6 Pillared clays. Preparation. Structure. Properties. Applications in catalysis. 2 7 Mesoporous materials. Silica based mesostructured materials. Synthesis 2 techniques. Properties. Incorporation of heteroatoms in the mesostructured silica. Non-siliceous mesostructured materials. 8 Applications in acid and redox catalysis. Anchoring of molecular catalysts to 2 the surface. 9 Layered double hydroxides. Composition. Structure. Synthesis techniques Hydrotalcites basicity. Applications in catalysis. 2 Conferinta si discutii. Metoda de predare a cursului Conference and discussions. Teaching Methods 2

3 Prezenţa şi pregătirea pentru cursuri Prezenţa la cursuri este o condiţie esenţială a bunei desfăşurări a întregii activităţi educaţionale. Participarea studenţilor este necesară întrucât o audiere directă îi ajută la o mai bună înţelegere a noţiunilor predate, la folosirea unui vocabular adecvat, le crează posibilitatea întreţinerii unui dialog interactiv precum şi a unei integrări în disciplina universitară. Lecture Preparation and Attendance The course attendance is a necessary condition of a good evolution of whole training process. The students attendance is necessary as a direct hearing helps to understand better the topics, to use an adequate vocabulary as well as creating the possibility of keeping an interactive dialogue and of integrating in academic discipline. Asistenţă în pregătirea examenelor Pentru o bună înţelegere a materiei predate şi pentru o implicare în învăţarea treptată a acestei materii, studenţii sunt supuşi unor teste periodice în timpul semestrului. Li se acorda consultaţii de către cadrele didactice care efectuează orele. Study Coaching For a better understanding of topics and for an involvement in graduated study of this discipline, the students are periodically tested during the semester. They can participate in tutorials given by academic staff responsible of this course. Conţinutul Activităţii aplicative Nr. lab. Tema laboratorului / seminarului Nr. ore 1 Interpretarea izotermelor de adsorbtie. Evidentierea tipului de porozitate. 4 2 Prepararea unui hidroxid dublu lamelar. 4 3 Prepararea silicei structurate mezoporoase. 4 4 Cataliza pe zeoliti. Selectivitatea conformationala. 4 5 Cataliza bazica pe hidrotalciti. Corelatii cu proprietatile fizico-structurale. 4 Contents of Applied Activity Nr. Lab. Subject of the laboratory / seminar Nr. hours 1 Interpretation of the adsorption isotherms. Evidencing the type of 4 porosity. 2 Preparation of a layered double hydroxide. 4 3 Preparation of a mesostructured silica. 4 4 Catalysis on zeolites. The shape-selectivity. 4 5 Basic catalysis on hydrotalcites. Correlations with the physico-structural properties. 4 Sistemul de evaluare a cunoştinţelor studenţilor La sfârşitul semestrului studenţii vor susţine un examen scris. La solicitarea studentilor examenul poate fi completat si cu o examinare orala. 3

4 Evaluation methods At the end of the semester the examination will be written. A supplementary oral examination can follow, at student request. Sistemul de notare Notarea se face în scara de note Examenul se consideră promovat cu nota 5. Activitatea Tip de cerinţă % din nota % nota finală pre-examen Prezenţa la curs Obligatorie - Prezenţa la laborator Obligatorie - Activitatea la laborator Obligatorie - Teste verificare curs Optional - Test final la laborator Obligatoriu Examen scris (oral optional) Obligatoriu - 80 Grading Grading will be between 1 and 10. The exam is considered to be graduated with grade 5. Activity Type or % of the preexam % final grade requirement grade Course attendance Compulsory - Lab attendance Compulsory - Lab activity Compulsory - Course tests Optional - Final lab test Compulsory Written examination (plus optionally oral) Compulsory - 80 Bibliografie selectivă Teaching and Learning Material Studenţilor li se recomandă consultarea urmatoarelor referinte bibliografice aflate în biblioteca facultăţii sau in biblioteca departamentului. The students are encouraged to further read the following references which can be found in School Library or Department Library. Nr. Bibliografie / References 1 H. van Bekkum, E. M. Flanigen, J.C. Jansen (eds.), Introduction to zeolite science and practice, Elsevier, A. Gil, L. M. Gandia, M. A. Vicente, Recent advances in the synthesis and catalytic applications of pillared clays, Catalysis Reviews Science & Engineering, 42 (2000) D. Trong On, D. Desplantier-Giscard, C. Danumah, S. Kaliaguine, Perspectives in catalytic applications of mesostructured materials, Applied Catalysis A: General, 253 (2003) A. Taguchi, F. Schuth, Ordered mesoporous materials in catalysis, Microporous and Mesoporous Materials, 77 (2004)

5 5 F. Cavani, F. Trifiro, A. Vaccari, Hydrotalcite-type anionic clays: preparation, properties and applications, Catalysis Today, 11 (1991) B. F. Sels, D. E. De Vos, P. A. Jacobs, Hydrotalcite-like anionic clays in catalytic organic reactions, Catalysis Reviews, 43(4) (2001) Serp, Ph., Figueiredo, J.L. (eds.), Carbon Materials for Catalysis, John Wiley & Sons, New Jersey, Ertl, G., Knözinger, H., Schüth, F., Weitkamp, J. (eds.), Handbook of Heterogeneous Catalysis, 8 volumes, 2 nd Edition, Wiley-VCH, Weinheim, Schüth, F., Sing, K. S. W., Weitkamp, J. (eds.), Handbook of Porous Solids, 5 volumes, Wiley-VCH, Weinheim, Data: 01/10/2012 DECAN Conf. Dr. Constantin Mihailciuc DIRECTOR DEPARTAMENT Prof. Dr. Vasile Parvulescu TITULAR DISCIPLINA Conf. Dr. Ioan-Cezar Marcu 5